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グラフェン、2D材料およびカーボンナノチューブ:市場・技術・市場機会:2018 - 2028年

Graphene, 2D Materials and Carbon Nanotubes: Markets, Technologies and Opportunities 2018-2028

発行 IDTechEx Ltd. 商品コード 249885
出版日 ページ情報 英文 349 Slides
納期: 即日から翌営業日
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グラフェン、2D材料およびカーボンナノチューブ:市場・技術・市場機会:2018 - 2028年 Graphene, 2D Materials and Carbon Nanotubes: Markets, Technologies and Opportunities 2018-2028
出版日: 2018年05月01日 ページ情報: 英文 349 Slides
概要

当レポートでは、グラフェンの技術および市場について調査し、グラフェン市場の発展の経緯と今後の展望、グラフェンの各種製造・加工技術、用途別の詳細分析と10カ年成長予測、主な市場動向と市場影響因子および市場機会の分析、主要企業へのインタビュー、主要企業のプロファイルなどをまとめています。

第1章 エグゼクティブサマリー

第2章 市場予測

  • 詳細なグラフェン市場10ヵ年予測:主要21のアプリケーション領域
  • グラフェン市場10ヵ年予測:アプリケーション区分別
  • グラフェン市場10ヵ年予測:プレートレット vs. シート
  • グラフェン市場の概要
  • グラフェンプレートレット10ヵ年需要の予測
  • MWCNTの10ヵ年市場予測:主要16アプリケーション (金額ベース)
  • MWCNTの10ヵ年市場予測:主要16アプリケーション (数量ベース)
  • SWCNT/DWCNT の10ヵ年市場予測:アプリケーション別 (金額ベース)
  • SWCNT/DWCNT の10ヵ年市場予測:アプリケーション別 (数量ベース)

第3章 中国における最新の発展動向

第4章 グラフェンの製造 (プレートレットタイプ)

  • エキスパンドグラファイト
  • 還元型酸化グラフェン
  • グラファイトの酸化:プロセス・特徴
  • 酸化グラフェンの還元:異なる方法
  • 直接液相剥離:プロセス・特徴
  • せん断力下の直接液相剥離
  • 電気化学剥離
  • 電気化学剥離グラフェンの特徴
  • プラズマ剥離
  • 無基板プラズマ
  • 無基板CVD (化学蒸着)
  • 無基板CVD

第5章 グラフェン製造 (フィルムタイプ)

  • フィルムタイプグラフェン向けCVD (化学蒸着)
  • CVDグラフェン
  • CVDグラフェンの成長プロセス
  • CVDグラフェン成長における酸素の主な役割、ほか

第6章 グラフェン・CNT材料の形態

  • グラフェン材料の図
  • CNT材料の図

第7章 グラフェン導電性インク

  • グラフェンプレートレット/パウダーベースの導体:導電性インク
  • 導電性グラフェンインクの用途
  • グラフェンインクによる抵抗加熱
  • 加熱の用途、ほか

第8章 スーパーキャパシター

  • スーパーキャパシターとは?
  • スーパーキャパシター:特徴およびエネルギー/出力密度のポジショニング
  • スーパーキャパシター:延長ライフサイクル
  • スーパーキャパシターの用途のパイプライン、ほか

第9章 Li-ion (リチウムイオン) 電池におけるグラフェンおよびCNT

  • リチウムイオン電池の発展の経緯
  • 電極質量:電池の種類別
  • リチウムイオン電池のコスト内訳
  • リチウムイオン電池におけるナノカーボンの理由、ほか

第10章 Si (シリコン) アノード電池におけるグラフェンおよびCNT

  • なぜシリコンアノード電池なのか?
  • シリコンアノード電池技術の概要
  • シリコンアノード電池の理由と主な課題は?
  • シリコンアノードにおけるグラフェンの役割、ほか

第11章 Li-S (リチウム硫黄) 電池におけるグラフェン

  • 動機付け:なぜリチウム硫黄電池なのか?
  • リチウム硫黄電池の化学
  • なぜグラフェンがリチウム硫黄電池に役立つのか
  • リチウム硫黄電池におけるグラフェンの最新の利用例、ほか

第12章 ポリマー複合材料におけるグラフェン

  • 複合材料におけるグラフェン添加剤の利用に関する調査
  • グラフェンプレートレット型導体:ポリマー複合材料
  • グラフェン導電性複合材料:商業的成果
  • ポリエステル・PETにおける導電性添加剤としてのグラフェン、ほか

第13章 プラスチック添加剤としてのCNT

  • 導電性複合材料におけるCNTの仕組み
  • 導電性複合材料としてのMWCNT
  • ポリマー複合材料導電性添加剤としてのCNTのサマリー
  • 導電性複合材料におけるCNTの成功、ほか

第14章 タイヤ

  • タイヤの添加剤としてのグラフェン
  • グラフェン対応二輪タイヤの進歩
  • タイヤにおけるカーボンブラック
  • 自動車タイヤにおけるブラックカーボン
  • 市場における各種カーボンブラック種類のマッピング、ほか

第15章 透明導電性フィルム・ガラスのイントロダクション

  • 透明導電性フィルム (TCF)
  • 各種TCF
  • ITOフィルムの評価:性能・メーカー・市場動向
  • ITOフィルムの欠点:柔軟性、ほか

第16章 CNT透明導電性フィルム

  • CNT透明導電性フィルム:性能
  • CNT透明導電性フィルム:市販フィルムの性能
  • CNT透明導電性フィルム:インデックスマッチング
  • CNT透明導電性フィルム:機械的柔軟性、ほか

第17章 TCFベンチマーキング・市場分析

  • 核TCF技術の定量的ベンチマーキング
  • 技術比較
  • 主要10技術の市場予測

第18章 複合材料

  • 複合材料へのグラフェン添加剤利用:概要
  • グラフェン導電性複合材料:商業的成果
  • グラフェン導電性複合材料:実験結果
  • EMI遮蔽
  • 導電性複合材料におけるCNTの作用
  • 導電性複合材料におけるCNTの成功
  • 導電性プラスチックへのCNT利用:製品の例、ほか

第19章 センサー

  • グラフェンGFETセンサー
  • 高速グラフェンフォトセンサー
  • グラフェン湿度センサー、ほか

第20章 その他の用途

  • 防食塗料
  • 水濾過
  • 将来の用途、ほか

第21章 トランジスター向けグラフェンおよび2D材料

第22章 企業プロファイル

目次

Title:
Graphene, 2D Materials and Carbon Nanotubes: Markets, Technologies and Opportunities 2018-2028
Granular ten-year market forecasts, data-driven and quantitative application assessment, 40+ interview-based company profiles, revenue/investment/capacity by player, and more.

This report offers a detailed analysis of the technological and commercial progress as well prospects of graphene, carbon nanotubes and non-graphene 2D materials.

This grouping of material technologies makes sense because graphene and CNTs, despite their morphological differences, have much in common; whilst non-graphene 2D materials promise to offer complementary properties.

Why IDTechEx for research on graphene, carbon nanotube and non-graphene 2D materials?

This report is the result of years of ongoing research. We launched the first version of our report on CNTs and graphene in 2011 and 2012, respectively. In addition to the initial research, we have organized 13 business-focused events on topic ourselves in Europe and USA; we have also since attended and/or lectured at 10 relevant non-IDTechEx conferences in Asia, Europe and USA; we have interviewed more than 140 players worldwide; we have delivered 12 masterclasses to business leaders; and we have completed 7 major consulting projects. All this gives us an excellent and unrivalled insight into these industries.

Another unique point of strength for us is that we have extensive in-depth coverage of the end-use markets for these materials. Indeed, we have a series of independent reports on such topics. Examples includes our works on Li-ion Batteries 2018-2028, Supercapacitor Technologies and Markets 2018-2028, Advanced Li-ion & Beyond Li-ion Batteries 2018-2028, Composites 2017-2027: Innovations, Opportunities, Market Forecasts, Thermal Interface Materials 2016-2026: Status, Opportunities, Market Forecasts, Printed and Flexible Sensors 2017-2027: Technologies, Players, Forecasts, RFID Forecasts, Players and Opportunities 2017-2027, and so on. This expertise on the end-use markets enables us to better understand the landscape in which these materials compete.

Carbon nanotubes: a brief overview

CNTs are almost thirty years old already. In this time, they have gone through almost the entire hype curve, rising from their academic origins toward their peak of hype before nearly disappearing into the valley of disillusionment. CNTs have however been making a quiet comeback and have now indeed entered a phase of volume growth.

As in graphene and many other similar carbon additive materials, there is no single type of CNT but there are many. The diameter of on-market CNTs range from near 1nm to several hundred, taking the CNTs from being singled-walled (SWCNT) towards multi-walled (MWCNTs) and carbon nanofibers. Similarly, the tube lengths range from few micro meters all the way to 2 millimetres.

Each of these CNTs is a different material: it is produced differently; it is processed differently, and it is used differently. This diversity is also reflected in prices which cover nearly six orders of magnitude (from highest cost SWCNT to lowest cost MWCNT).

Evolution of MWCNT markets: quietly entering the volume growth phase

MWCNTs are mainly produced using the C-CVD process (catalytic chemical vapor deposition). The evolution of accumulated global production for MWCNTs is shown below. Note here that the commercialization efforts start around 2005/2006. The super hype then sets in, leading to a rush to install capacity. This pushes the industry into a state of overcapacity, and still worse, pushes many to produce a CNT that is not good enough to meaningfully displace carbon black or similar.

As a result, faced with disappointing prospects, some leave the business, leading to some correction in overall capacity. The global capacity then generally remains constant as some enter and leave. Importantly however, the utilization rate slowly begins to rise.

Our analysis is now that the market has entered a period of volume growth. MWCNT use in conductive plastic applications is now well established and is expanding. It is also being added to new polymers like elastomers. More importantly, it is being used more in batteries. This is more important because the battery market is an escalator market in that it itself is poised for rapid growth thanks to uptake of electric vehicles demanding large batteries operating in high charge-discharge regimes.

In general, like most carbon-based materials, CNTs have diverse target markets, giving resilience to their prospects. The growth in demand, we assess, will manifest itself soon as increased capacity. This process already begun when a multi-hundred-tonne facility came online in Asia a little over a year ago. This trend will continue.

Left: historical and projected price evolution of MWCNTs as a function time. The exact values have been removed in this article, but you can see that prices were reduced nearly by nearly a factor of 100. Right: global accumulated production capacity as a function time, telling the story of the market evolution. Source: IDTechEx Research

Like graphene, CNTs are often a substitute additive. As such, they must compete on price and performance against the reference market values set by the incumbent. This gives rise to a perennial downward cost pressure. The industry has therefore had no choice but to cut cost of production. And in that regard, it has had good success.

This is shown in the chart here, also showing the price evolution of CNTs. The blue dots show historic prices whilst red ones are our future projections: the learning curve is steep with prices having fallen by 2 orders of magnitude.

This competition on price and volume has largely commoditized the MWCNT supply business. We however do not mean that all differences in material quality have disappeared since many varieties of MWCNTs are on the market. The differences in quality, depending on application, will manifest themselves as small price differentials enabling the market to retain some of its speciality chemical character.

SWCNT become more available and affordable?

The CNT story is not all about MWCNTs. Indeed, SWCNT have superior performance on an individual tube basis given their higher surface-to-volume ratio. They are however more difficult and expensive to grow, come as mixed metallic and semiconducting types, and are much harder to disperse even though the wt% levels involved for the same or better effect might be much lower. These three attributes have combined to keep its market limited to some niche electronic devices.

Some companies are now seeking to change this by offering a more affordable and available SWCNT. Price and volume leaders are emerging, hoping to push SWCNTs closer to high-performance MWCNT in their market positioning. These SWCNT may compete with MWCNT as a substitute in some applications, but, more interestingly, they will open new applications despite their moderate-to-high impurity levels (in the as-grown versions).

One interesting application is that they can enable coloured (vs. black) conductive adhesives owing to their ultra-low loading levels. We assess that this and similar SWCNT will first find markets where they deliver this type of additional value to customers as they still cannot compete on cost directly.

Graphene: Finally moving out of the lab and into the market?

Graphene is also going through its own hype curve. It is arguably now in that disillusionment valley. Graphene commercialization is however making steady progress. This can be summarized in the key trend below:

  • Increasing industry experience: In the early days graphene was oversold as a wonder material or a magic dust that would overnight revolutionize just about every industry. Naturally, with time, realism has set in. Today, graphene platelets are increasingly, and rightly, viewed as part of the expansive continuum of carbon additive materials.

Furthermore, the market now realizes that there are many graphene materials and not all are equal. As such, the users now accept that the winning materials cannot be determined a priori as final application-level results are influenced by many parameters such as graphene morphology and formulation/compounding technique and conditions.

  • Increasing availability: Graphene has diverse useful properties and as a result a diverse application pipeline. Most target applications however are volume markets. Therefore, suppliers have had to take the risk to invest in sizable production in the face of small and uncertain demand. This has been inevitable because otherwise suppliers could never progress past the phase of prototyping or performance demonstration. This process (of installing capacity) has made such significant progress worldwide that availability, in the medium term, is not a major industry concern.

Interesting, and as now is familiar in many industries, China has become the leading territory in terms of nominal production capacity. Its rise to prominence has also made direct liquid phase exfoliation the leading process by share of production capacity. This is because many Chinese producers were not part of the first wave of graphene companies who relied upon the then-available rGO process.

  • Increasing affordability: Similar to CNTs, graphene is largely a substitute material. As such, it must compete on price as well as performance with incumbent solutions. As a new specialty material, graphene suffered from high and divergent (by orders of magnitude) prices and pricing strategies.

This has changed. Graphene platelet prices have fallen and are beginning to converge, for now. The prices will however not settle around a single point, reflecting the diversity of graphene types and giving it a speciality chemical character. Furthermore, suppliers will be reluctant to further cut costs out of fear of premature commoditization although the continuation of this trend has an air of inevitability to it.

  • Increasing revenue and volume sales progress: Our data suggest that income at the graphene company level has been rising steadily since 2013. This rise, which is reflected largely across the board, will continue at similar rates until 2020/21 around which time our model suggests an inflection point will occurs, putting the market into its rapid volume growth phase.
  • This rise in revenue however has not been always accompanied with increasing profit. In fact, the opposite is often true in that losses have grown in line with revenues. Indeed, the industry, as a whole, is still loss making despite the existence of several profitable companies.

This is no surprise but is likely to soon change. Experience has demonstrated that new materials take years, if not decades, to commercialize. Graphene is also no exception therefore this behaviour is in our view a natural part of growth process of the industry.

We forecast that a circa. $300M market, at the material supply level, will be formed within the next ten years. Since graphene is still largely an additive material, this means that we will find graphene, of different types, in numerous volume applications in the years to come. This success, it is worth remembering, will not have come overnight but will have been the results of almost two decades of steadfast global research and commercialization efforts.

Non-graphene 2D materials?

These materials are still largely in the academic phase. They however hold enormous long-term promise in that they can complement the properties of graphene. They can, for example, add insulating or semiconducting (with sizable bandgaps) 2D materials to the menu of material options. In this report, we will outline some of the latest progress here in particular focusing on the need they serve in future electronic applications.

What does this report provide?

This report provides the following:

Introduction and business dynamics/trends

  • Disparity between ideal and non-ideal graphene and CNTs
  • Diversity of graphene and various CNT morphologies on the market
  • Pricing evolutions, trends and strategies worldwide for graphene and various CNTs
  • Nominal production capacity by supplier worldwide for graphene and various CNTs
  • Categorization of graphene and CNT manufacturers by production processes
  • Various trends such as publication, patent filing, etc
  • Trends in company revenue and profit/loss
  • Companies valuation trends
  • Specific look on China (for graphene) covering key emerging Chinese suppliers, applications and prices
  • Applications examples, pipeline and readiness levels for graphene and CNTs

Ten-year segmented market forecasts

  • Ten-year application-segmented market projections for graphene (platelet and film) in tonnes and value.

Here, we cover energy storage (li ion, silicon anode, LiS, supercapacitor and other); composites (mechanically-enhanced, permeation-enhanced, conductive, thermal, EMI shielding, conductive 3D printing filaments, tire, other); inks and coatings (anti-corrosion coating, RFID antenna, other); transistors, transparent conductive films, thermal interface materials and so on.

  • Ten-year application-segmented market projections for MWCNTs in tonnes and value

Here we cover electric vehicle and consumer electronic Li ion batteries, supercapacitors, CNT additives for automotive fuel lines and car body part painting, CNTs for IC trays and similar; other conductive polymer; non-tire rubber additives; tire additives; thin film transistors; transparent conductive films; cable screen shield; and cable replacement.

  • Ten-year application-segmented market projections for SWCNT/FWCNT in tonnes and value. Here we cover the same application as above.

Review of production processes

  • Graphene: rGO, direct liquid phase exfoliation, plasma, substrate-less CVD, substrate-based CVD and transfer (film type)
  • Carbon nanotubes: laser ablation, arc discharge, catalytic chemical vapour deposition, vertically-aligned growth, etc

Application assessment

  • Conductive inks: performance position vs metallic and carbon inks and results-based review of applications such as heating, EMI shielding coatings/films, UV-protecting films, anti-corrosion coatings, RFID antennas, printed sensor electrodes, and so on
  • Supercapacitors: Analysis of supercapacitor devices and their applications; review of results based on graphene and CNTs; assessment of remaining challenges; and overview of various electrode chemistries on the market based on patent analysis
  • Batteries: assessment of the need and challenges in various battery technologies (Li ion, silicon anode Li ion, Li sulphur, etc) and results-based review of role of graphene and CNTs in various batteries as both anode and cathode additives
  • Polymer composites: role of graphene and CNTs as multi-functional (thermal, conductive, permeation, strength enhancement etc) additives in polymers and results-based review of their impact in various polymeric hosts such as PS, PET, PET, ABS, PP, PMMA, PDMS, Epoxy, PC, PI, HDPS, and so on.
  • Other applications including transparent conducting films (with a special focus on film-type CVD graphene), sensors, transistors (with a special focus on 2D materials), tires, water filtration, memory, and so on.

Companies

Here we provide interview-based insights into over 100 companies. For a full list see the table of content below.

Analyst access from IDTechEx

All report purchases include up to 30 minutes telephone time with an expert analyst who will help you link key findings in the report to the business issues you're addressing. This needs to be used within three months of purchasing the report.

Table of Contents

1. EXECUTIVE SUMMARY

  • 1.1. Not all graphenes are equal: diversity is intrinsic to the material system
  • 1.2. Trade-offs involved between different production processes
  • 1.3. Explaining the main graphene manufacturing routes
  • 1.4. Quantitative mapping of graphene morphologies on the market (lateral size vs thickness)
  • 1.5. General observations on the market situation
  • 1.6. The hype curve of the graphene industry
  • 1.7. Graphene suppliers categorised by production process (direct exfoliation, rGO, CVD(powder), Plasma, CVD (film), etc.)
  • 1.8. Trends in publications for graphene and other 2D materials
  • 1.9. Large scale investment in graphene research
  • 1.10. Investment in new graphene companies split by specific companies
  • 1.11. Revenue of graphene companies split by 40 specific companies
  • 1.12. Profit and loss of graphene companies from 2013 to 2016
  • 1.13. Value creation for graphene companies: a look at public valuation trends
  • 1.14. The rise of China in graphene (production capacity figures of Chinese graphene manufacturers)
  • 1.15. Patent trends for grapehene: past peak activity?
  • 1.16. Top 15 patent holders: dominance of Asia is clear
  • 1.17. Graphite mines see opportunity in graphene
  • 1.18. Graphene platelet-type: global production capacity by company and split by region and production process type
  • 1.19. The importance of intermediaries
  • 1.20. Graphene platelet-type: pricing trends by supplier and production process
  • 1.21. Quality and consistency issue
  • 1.22. Graphene platelet/powder-based conductors: conductive inks
  • 1.23. Graphene platelet-based conductors: polymer composites
  • 1.24. Graphene: LFP cathode improvement
  • 1.25. Application timeline
  • 1.26. Graphene products and prototypes
  • 1.27. Graphene-enabled sports equipment
  • 1.28. Graphene enabled lithium ion batteries
  • 1.29. Graphene-enabled supercapacitors
  • 1.30. Graphene-enabled lead acid battery
  • 1.31. Graphene-enhanced conductive 3D printing filaments
  • 1.32. Graphene-enabled bike tires
  • 1.33. Graphene-enabled RFIDs and flexible interconnects
  • 1.34. Heating applications
  • 1.35. Graphene-enabled anti-corrosion applications
  • 1.36. ESD films
  • 1.37. Graphene-enabled stretch sensor applications
  • 1.38. Graphene-enabled textile applications
  • 1.39. Graphene-enabled vehicle tire
  • 1.40. Graphene-enabled conductive adhesives and inks
  • 1.41. Graphene-enabled guitar strings and lubricants
  • 1.42. Graphene-enabled transparent conducting film applications
  • 1.43. Graphene-enabled stretch sensor applications
  • 1.44. Introduction to Carbon Nanotubes (CNT)
  • 1.45. CNTs: ideal vs reality
  • 1.46. Not all CNTs are equal
  • 1.47. Price position of CNTs (from SWCNT to FWCNT to MWCNT)
  • 1.48. Price evolution: past, present and future (MWCNTs)
  • 1.49. Production capacity of CNTs globally
  • 1.50. The evolution of accumulated global production capacity from 2016 to 2018
  • 1.51. CNTs: value proposition as an additive material
  • 1.52. CNT: snapshot of market readiness levels of CNT applications
  • 1.53. CNT-polymer composite: performance levels in different polymers
  • 1.54. Conductive plastics: application examples
  • 1.55. Graphene vs. Carbon nanotubes: general observations

2. MARKET PROJECTIONS

  • 2.1. Granular ten year graphene market forecast segmented by 21 application areas
  • 2.2. Ten-year application-segmented graphene market forecast
  • 2.3. Ten-year forecast for graphene platelet vs sheets
  • 2.4. Granular snapshot of the graphene market in 2018
  • 2.5. Granular snapshot of the graphene market in 2029
  • 2.6. Ten-year forecast for volume (MT) demand for graphene platelets
  • 2.7. Ten-year market forecast for MWCNTs segmented by 16 applications in value
  • 2.8. Ten-year market forecast for MWCNTs segmented by 16 applications in tonnes
  • 2.9. Ten-year market forecast for SWCNTs/DWCNTs segmented by application in value
  • 2.10. Ten-year market forecast for SWCNTs/DWCNTs segmented by application in tonnes

3. OVERVIEW OF LATEST DEVELOPMENTS IN CHINA

  • 3.1. The rise of China in graphene (production capacity figures)
  • 3.2. SuperC Technology Limited: Already making headway in energy storage
  • 3.3. Ningbo Morsh: One of the largest graphene producers?
  • 3.4. 2D Carbon (Changzhou)Ltd
  • 3.5. Sixth Element: one of the largest rGO players
  • 3.6. Ningbo Soft Carbon Electronics: R2R CVD graphene growth and transfer
  • 3.7. Wealtech/MITBG: Graphene as heating element
  • 3.8. Tungshu (Dongxu Optoelectronic Technology)
  • 3.9. Deyang Carbonene: Exfoliated graphene for heating
  • 3.10. Other companies: ENN, Nanjing SCF Nanotech Ltd, Hongsong Technology
  • 3.11. Other companies: Liaoning Mote Graphene Technology, Shandon Yuhuang New Energy Technology, Changsha Research Institute of Mining & Metallurgy

4. GRAPHENE PRODUCTION (PLATELET TYPE)

  • 4.1. Expanded graphite
  • 4.2. Reduced graphene oxide
  • 4.3. Oxidising graphite: processes and characteristics
  • 4.4. Reducing graphene oxide: different methods
  • 4.5. Direct liquid phase exfoliation: process and characteristics
  • 4.6. Direct liquid phase exfoliation under shear force
  • 4.7. Electrochemical exfoliation
  • 4.8. Properties of electrochemical exfoliated graphene
  • 4.9. Plasma exfoliation
  • 4.10. Substrate-less Plasma
  • 4.11. Substrate-less CVD (chemical vapour deposition)
  • 4.12. Substrate-less CVD: growth of flower like graphene

5. GRAPHENE PRODUCTION (FILM TYPE)

  • 5.1. Chemical vapour deposition (CVD) for film-type graphene
  • 5.2. CVD Graphene
  • 5.3. Growth process of CVD graphene
  • 5.4. The key role of oxygen in CVD graphene growth
  • 5.5. Roll to roll (R2R) growth of CVD graphene film
  • 5.6. The transfer challenge: a showstopper?
  • 5.7. Roll-to-roll transfer of CVD graphene
  • 5.8. Novel methods for transferring CVD graphene
  • 5.9. Using R2R joule heating to enable CVD growth
  • 5.10. Epitaxial: high performance but high cost
  • 5.11. Largest single-crystalline graphene reported ever
  • 5.12. Different production processes (laser ablation and arc discharge)
  • 5.13. Different production processes (catalytic CVD)
  • 5.14. Different production processes (wafer or sheet based catalytic growth)
  • 5.15. Varieties of vertically-aligned pure CNTs
  • 5.16. Benchmarking of different CNT production processes

6. MORPHOLOGY OF GRAPHENE AND CNT MATERIALS

  • 6.1. Pictures of graphene materials
  • 6.2. Pictures of CNT materials

7. GRAPHENE CONDUCTIVE INKS

  • 7.1. Graphene platelet/powder-based conductors: conductive inks
  • 7.2. Applications of conductive graphene inks
  • 7.3. Results of resistive heating using graphene inks
  • 7.4. Heating applications
  • 7.5. Uniform and stable heating
  • 7.6. Results of de-frosting using graphene inks
  • 7.7. Results of de-icing using graphene heaters
  • 7.8. Transparent EMI shielding
  • 7.9. ESD films printed using graphene
  • 7.10. Graphene UV shielding coatings
  • 7.11. Graphene inks can be highly opaque
  • 7.12. RFID types and characteristics
  • 7.13. UV resistant tile paints
  • 7.14. Graphene RFID tags: already a success story?
  • 7.15. Overview of RFID antennas
  • 7.16. Overview of the general RFID antenna market figures
  • 7.17. Cost breakdown of RFID tags
  • 7.18. Methods of producing RFID antennas
  • 7.19. Graphene in glucose test strips
  • 7.20. Printed glucose: what is it?
  • 7.21. Anatomy of a test strip: one example
  • 7.22. Profitability in the test strip industry is falling
  • 7.23. Big four test strip manufacturers are changing to counter decreasing profitability
  • 7.24. Market projections for glucose test strips

8. SUPERCAPACITORS

  • 8.1. Supercapacitors: what are they?
  • 8.2. Supercapacitors: attributes and energy/power density positioning
  • 8.3. Supercapacitors: extended cycle life
  • 8.4. Application pipeline for supercapacitors
  • 8.5. Cost structure of a supercapacitor
  • 8.6. Cost breakdown of supercapacitors
  • 8.7. Supercapacitor electrode mass and cost in transport applications
  • 8.8. Why graphene in supercapacitors?
  • 8.9. Challenges with graphene: surface area is far from the ideal case
  • 8.10. Challenges with graphene: poor out-of-plane conductivity and re-stacking
  • 8.11. Nanocarbons in supercapacitors: pushing the performance envelope
  • 8.12. Promising results on GO supercapacitors
  • 8.13. Promising results on graphene supercapacitors
  • 8.14. Skeleton Technologies' graphene supercapacitors
  • 8.15. Performance of carbon nanotube supercapacitors
  • 8.16. Potential benefits of carbon nanotubes in supercapacitors
  • 8.17. Binder-free CNT film as supercapacitor electrode
  • 8.18. Challenges with the use of carbon nanotubes
  • 8.19. Electrode chemistries of supercapacitor suppliers

9. GRAPHENE AND CNTS IN LI ION BATTERIES

  • 9.1. Historical progress in Li ion batteries
  • 9.2. Electrode mass by battery type
  • 9.3. Cost breakdown of Li ion batteries
  • 9.4. Why nanocarbons in Li batteries
  • 9.5. Why graphene and carbon black are used together
  • 9.6. LFP cathode improvement (PPG Industry)
  • 9.7. Results showing graphene improves LFP batteries (Graphene Batteries)
  • 9.8. Results showing graphene improves NCM batteries (Cabot Corp)
  • 9.9. Results showing graphene improves LiTiOx batteries
  • 9.10. Results showing CNT improves the performance of commercial Li ion batteries (Showa Denko)
  • 9.11. Results showing SWCNT improving in LFO batteries (Ocsial)
  • 9.12. Mixed graphene/CNT in batteries

10. GRAPHENE AND CNTS IN SI ANODE BATTERIES

  • 10.1. Why Silicon anode batteries?
  • 10.2. Overview of Si anode battery technology
  • 10.3. Why silicon anode battery and key challenges?
  • 10.4. Graphene's role in silicon anodes
  • 10.5. Why graphene helps in Si anode batteries: results and strategies
  • 10.6. State of the art results in silicon-graphene anode batteries
  • 10.7. State of the art in silicon-graphene anode batteries (PPG Industries)
  • 10.8. State of the art in silicon-graphene anode batteries (XG Sciences and SiNode)
  • 10.9. State of the art in silicon-graphene anode batteries (CalBatt)
  • 10.10. Samsung's result on Si-graphene batteries
  • 10.11. State of the art in silicon-graphene anode batteries

11. GRAPHENE IN LIS BATTERIES

  • 11.1. Motivation - Why Lithium Sulphur batteries?
  • 11.2. The Lithium sulphur battery chemistry
  • 11.3. Why graphene helps in Li sulphur batteries
  • 11.4. State of the art in use of graphene in Li Sulphur batteries
  • 11.5. State of the art in use of graphene in Li Sulphur batteries (Oxis Energy/Perpetuus Advanced Materials)
  • 11.6. State of the art use of graphene in Li Sulphur batteries (Lawrence Berkeley National Laboratory)
  • 11.7. Graphene battery announcement (Grabat)
  • 11.8. Yuhuang's graphene-enabled battery

12. GRAPHENE IN POLYMER COMPOSITES

  • 12.1. General observation on using graphene additives in composites
  • 12.2. Graphene platelet-based conductors: polymer composites
  • 12.3. Commercial results on graphene conductive composites (Nylon 66): the impact of aspect ration
  • 12.4. Graphene as conductive additive in Polyester and PET
  • 12.5. Graphene as conductive additive in PMDS, Natural Rubber and Epoxy
  • 12.6. Graphene as conductive additive in PUA, PC, PDMS
  • 12.7. Conductivity improvement in HDPE
  • 12.8. EMI Shielding: graphene additives in epoxy
  • 12.9. Results showing Young's Modulus enhancement using graphene
  • 12.10. Commercial results on permeation graphene improvement
  • 12.11. Permeation Improvement
  • 12.12. Commercial results on thermal conductivity improvement using graphene
  • 12.13. Thermal conductivity improvement using graphene

13. CNT AS PLASTIC ADDITIVE

  • 13.1. How do CNTs do in conductive composites
  • 13.2. MWCNTs as conductive additives
  • 13.3. Summary of CNT as polymer composite conductive additive
  • 13.4. Summary of CNT as polymer composite conductive additive
  • 13.5. CNT success in conductive composites
  • 13.6. Examples of products that use CNTs in conductive plastics
  • 13.7. Tensile strength: Comparing random vs aligned CNT dispersions in polymers
  • 13.8. Elastic modulus: Comparing random vs aligned CNT dispersions in polymers
  • 13.9. Thermal conductivity: using CNT additives

14. TIRES

  • 14.1. Graphene as additive in tires
  • 14.2. Progress on graphene-enabled bicycle tires
  • 14.3. Carbon black in tires
  • 14.4. Black carbon in car tires
  • 14.5. Mapping of different carbon black types on the market
  • 14.6. CNT and graphene are the least ready emerging tech for tire improvement
  • 14.7. Results on use of graphene in silica loaded tires
  • 14.8. Comments on CNT and graphene in tires
  • 14.9. Total addressable market for graphene in tires

15. INTRODUCTION TO TRANSPARENT CONDUCTIVE FILMS AND GLASS

  • 15.1. Transparent conducting films (TCFs)
  • 15.2. Different Transparent Conductive Films (TCFs)
  • 15.3. ITO film assessment: performance, manufacture and market trends
  • 15.4. ITO film shortcomings: flexibility
  • 15.5. ITO film shortcomings: limited sheet conductivity
  • 15.6. ITO films: current prices (2018)
  • 15.7. Indium's single supply risk: real or exaggerated?
  • 15.8. Silver nanowire transparent conductive films: principles
  • 15.9. Silver nanowire transparent conductive films: performance levels and value proposition
  • 15.10. Silver nanowire transparent conductive films: flexibility
  • 15.11. Metal mesh transparent conductive films: operating principles
  • 15.12. Metal mesh: photolithography followed by etching
  • 15.13. Fujifilm's photo-patterned metal mesh TCF
  • 15.14. Embossing/Imprinting metal mesh TCFs
  • 15.15. Komura Tech: improvement in gravure offset printed fine pattern (<5um) metal mesh TCF ?
  • 15.16. Graphene performance as TCF
  • 15.17. Doping as a strategy for improving graphene TCF performance
  • 15.18. Be wary of extraordinary results for graphene
  • 15.19. Graphene transparent conducting films: flexibility
  • 15.20. Graphene transparent conducting films: thinness and barrier layers
  • 15.21. Wuxi Graphene Film Co's CVD graphene progress
  • 15.22. LG Electronics: R2R CVD graphene targeting TCFs?
  • 15.23. Ningbo Soft Carbon Electronics: R2R CVD graphene growth and transfer
  • 15.24. 2D Carbon (Changzhou)Ltd: Moving away from CVD type graphene film?
  • 15.25. Other players

16. CNT TRANSPARENT CONDUCTIVE FILMS

  • 16.1. Carbon nanotube transparent conductive films: performance
  • 16.2. Carbon nanotube transparent conductive films: performance of commercial films on the market
  • 16.3. Carbon nanotube transparent conductive films: matched index
  • 16.4. Carbon nanotube transparent conductive films: mechanical flexibility
  • 16.5. Carbon nanotube transparent conductive films: stretchability as a key differentiator for in-mould electronics
  • 16.6. Example of 3D touch-sensing surface with CNTs
  • 16.7. Example of wearable device using CNT
  • 16.8. Key players

17. TCF BENCHMARKING AND MARKET ANALYSIS

  • 17.1. Quantitative benchmarking of different TCF technologies
  • 17.2. Technology comparison
  • 17.3. 2018-2028 Market forecasts segmented by 10 technologies (value)

18. COMPOSITES

  • 18.1. General observation on using graphene additives in composites
  • 18.2. Commercial results on graphene conductive composites
  • 18.3. Experimental results on graphene conductive composites
  • 18.4. EMI Shielding
  • 18.5. How do CNTs do in conductive composites
  • 18.6. CNT success in conductive composites
  • 18.7. Examples of products that use CNTs in conductive plastics
  • 18.8. Results showing Young's Modulus enhancement using graphene
  • 18.9. Commercial results on permeation graphene improvement
  • 18.10. Permeation Improvement using graphene
  • 18.11. Thermal conductivity improvement using graphene, SWCNT and graphite as a function of wt% and vol%
  • 18.12. Commercial results on thermal conductivity improvement using graphene
  • 18.13. Thermal conductivity improvement using graphene

19. SENSORS

  • 19.1. Graphene GFET sensors
  • 19.2. Fast graphene photosensor
  • 19.3. Graphene humidity sensor
  • 19.4. Optical brain sensors using graphene
  • 19.5. Graphene skin electrodes
  • 19.6. Wearable stretch sensor using graphene

20. OTHER APPLICATIONS

  • 20.1. Anti-corrosion coating
  • 20.2. Imagine Intelligent Textiles geotextile graphene
  • 20.3. Water filtration
  • 20.4. Lockheed Martin's water filtration
  • 20.5. Nantero/Fujitsu CNT memory
  • 20.6. Lintec NTSC CNT sheets
  • 20.7. Future applications

21. GRAPHENE AND 2D MATERIALS FOR TRANSISTORS

  • 21.1. What are transistors?
  • 21.2. Transistor Figures-of-Merit: Transfer characteristics
  • 21.3. Transistor Figures-of-Merit: Output characteristics
  • 21.4. Graphene: the bandgap issue
  • 21.5. Actually performance of graphene transistors
  • 21.6. Actual performance of graphene transistors
  • 21.7. Graphene transistor based on work function modulation
  • 21.8. A range of two materials exist with bandgaps!
  • 21.9. Mobility of 2D materials as a function of bandgap
  • 21.10. Other 2D materials actually work as transistors
  • 21.11. Do 2D materials offer mobility (speed) advantage?
  • 21.12. The point of 2D materials as transistors: 5nm gate & beyond?
  • 21.13. The point of 2D materials as transistors: large area flexible TFTs?
  • 21.14. Stacked materials held together by Van der Waals forces
  • 21.15. Exfoliation non-graphene 2D materials
  • 21.16. Boron Nitride exfoliated
  • 21.17. What it all means for 'future' printed electronics?
  • 21.18. Some words on CVD non-graphene 2D materials
  • 21.19. Effect of growth method on mobility

22. COMPANY PROFILES

  • 22.1. 2D Carbon (Changhzou) Ltd
  • 22.2. Abalonyx
  • 22.3. Advanced Graphene Products
  • 22.4. AIST
  • 22.5. Alpha Assembly
  • 22.6. AMO GmbH
  • 22.7. Anderlab Technologies Pvt. Ltd
  • 22.8. Angstron
  • 22.9. Applied Graphene Materials
  • 22.10. Arkema
  • 22.11. AzTrong
  • 22.12. Bayer
  • 22.13. biDimensional
  • 22.14. Birla Carbon
  • 22.15. Bluestone Global Tech
  • 22.16. Bosch
  • 22.17. Brewer Science
  • 22.18. BTU International
  • 22.19. Cabot Corp
  • 22.20. Cambridge Graphene Centre
  • 22.21. Cambridge Nanosystems
  • 22.22. Canatu
  • 22.23. Carbon Waters
  • 22.24. CealTech
  • 22.25. Changsha Research Institute of Mining and Metallurgy
  • 22.26. Charmtron
  • 22.27. Chasm (ex SWeNT)
  • 22.28. Cnano
  • 22.29. CNM Technologies GmbH
  • 22.30. CPI Graphene Centre
  • 22.31. Deyang Carbonene
  • 22.32. Directa Plus
  • 22.33. Enerage
  • 22.34. Enerize Corporation
  • 22.35. ENN
  • 22.36. Ford
  • 22.37. g2o
  • 22.38. Garmor
  • 22.39. Global Graphene Group
  • 22.40. Gnanomat
  • 22.41. Gnext
  • 22.42. Grafoid
  • 22.43. Graphenano
  • 22.44. Graphene Batteries
  • 22.45. Graphene Devices
  • 22.46. Graphene Frontier
  • 22.47. Graphene Laboratories, Inc
  • 22.48. Graphene Square
  • 22.49. Graphene Technologies
  • 22.50. Graphenea
  • 22.51. Grupo Antoline
  • 22.52. Haydale
  • 22.53. Heraeus
  • 22.54. Hitachi Zosen
  • 22.55. Hongsong Technology
  • 22.56. IBM
  • 22.57. Incubation Alliance
  • 22.58. JC Nano
  • 22.59. Jeio
  • 22.60. Jinan Moxi New Material Technology
  • 22.61. KH Chemical
  • 22.62. LG Chem
  • 22.63. Liaoning Mote Graphene
  • 22.64. Lockheed Martin
  • 22.65. London Graphene Ltd
  • 22.66. Momentive
  • 22.67. Nanjing SFC Nanotech
  • 22.68. Nanocyl
  • 22.69. Nanomedical Diagnostics
  • 22.70. NanoXplore
  • 22.71. Nantero
  • 22.72. Ningbo Morsh
  • 22.73. Ningbo Soft Carbon Electronics
  • 22.74. Nippon Chemicon
  • 22.75. Nokia
  • 22.76. Ocsial
  • 22.77. Perpetuus
  • 22.78. Poly-Ink
  • 22.79. PPG Industries
  • 22.80. Pyrograf
  • 22.81. Raymor Industries
  • 22.82. Samsung
  • 22.83. Shandom Yuhuang New Energy Technology
  • 22.84. Showa Denko
  • 22.85. SiNode
  • 22.86. Sixth Element
  • 22.87. Skeleton Technologies
  • 22.88. Sony
  • 22.89. Solan PV
  • 22.90. Spirit Aerosystem
  • 22.91. Standard Graphene
  • 22.92. SuperC technologies
  • 22.93. Thomas Swan
  • 22.94. Timesnano
  • 22.95. Toray Industries
  • 22.96. Tungshu
  • 22.97. Unidym
  • 22.98. USDA Forest Product Laboratory
  • 22.99. Versarien
  • 22.100. Vorbeck Materials
  • 22.101. Wealtech/MITBG
  • 22.102. William Blythe Ltd
  • 22.103. Wuxi Graphene Film
  • 22.104. XFNAno
  • 22.105. XG Sciences
  • 22.106. Xiamen Knano
  • 22.107. Zyvex
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